Selenide borate

Selenide borates, officially known as borate selenides, are chemical mixed anion compounds that contain any kind of borate and selenide ions. They are distinct from selenoborates in which selenium atoms replace oxygen in borates. There are also analogous borate sulfides, with sulfur ions instead of selenium.

List

name chem mw crystal system space group unit cell volume density comments references
Zn8Se2[BO2]12 I43m a=7.6749 b=7.6749 c=7.6749 band gap 4.42 eV SHG 0.14xKDP [1][2]
YSeBO2 210.68 orthorhombic Cmc21 a=5.6617 b=16.5858 c=1.441 Z=4 389.15 3.596 band gap 3.45 eV [3]
Sm6Ta2MgSeB8O26 1869.75 trigonal P3 a=8.089 c=8.6765 Z=1 491.70 6.314 [4]
Eu6Ta2MgSeB8O26 1879.41 trigonal P3 a=8.0717 c=8.6491 Z=1 488.01 6.395 [4]
Gd6Ta2MgSeB8O26 1911.15 trigonal P3 a=8.0536 c=8.6296 Z=1 484.73 6.547 [4]

References

  1. ^ Zhou, Wenfeng; Li, Xiao-Hui; Yao, Wen-Dong; Xue, Huaiguo; Guo, Sheng-Ping (2020), CSD 1999764: Experimental Crystal Structure Determination, FIZ Karlsruhe - Leibniz Institute for Information Infrastructure, doi:10.5517/ccdc.csd.cc253xjr, retrieved 2021-03-13
  2. ^ Zhou, Wenfeng; Li, Xiao-Hui; Yao, Wen-Dong; Xue, Huaiguo; Guo, Sheng-Ping (October 2020). "Second-order nonlinear optical-active selenide borate Zn8Se2(BO2)12: Experimental and theoretical analysis". Journal of Solid State Chemistry. 290: 121572. Bibcode:2020JSSCh.29021572Z. doi:10.1016/j.jssc.2020.121572. S2CID 224876635.
  3. ^ Lu, Zhen-Tao; Fan, Wen-Jing; Wang, Zhi-Qian; Gu, Ning; Yue, Zeng-Hao; Xue, Huai-Guo; Guo, Sheng-Ping (2020-06-15). "Second-Order Nonlinear-Optical-Active Selenide Borate YSeBO 2 : Featuring a [YSeBO 2 ] n Planar Belt". Inorganic Chemistry. 59 (12): 7905–7909. doi:10.1021/acs.inorgchem.0c00753. ISSN 0020-1669. PMID 32469211. S2CID 218984948.
  4. ^ a b c Shi, Zhi-Hui; Chi, Yang; Yang, Mei; Liu, Wenlong; Guo, Sheng-Ping (2020-03-16). "A Series of Chalcogenide Borates RE 6 Ta 2 MgQB 8 O 26 (RE = Sm, Eu, Gd; Q = S, Se) Featuring a B 4 O 10 Cluster". Inorganic Chemistry. 59 (6): 3532–3536. doi:10.1021/acs.inorgchem.0c00086. ISSN 0020-1669. PMID 32090554. S2CID 211263182.
  • v
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Salts and covalent derivatives of the selenide ion
H2Se
H2Se2
+H
-H 		He
Li2Se Be SexByOz CSe2
OCSe
(CH3)2Se 		(NH4)2Se O F Ne
Na2Se MgSe Al2Se3 Si PxSey
-P 		+S Cl Ar
K2Se CaSe Sc2Se3 TiSe2 V CrSe
Cr2Se3 		MnSe
MnSe2 		FeSe CoSe NiSe CuSe ZnSe GaSe
Ga2Se3
-Ga 		GeSe
GeSe2
-Ge 		As2Se3
As4Se3 		Se2−
n 		Br Kr
Rb2Se SrSe Y2Se3 Zr NbSe2
NbSe3 		MoSe2 Tc Ru Rh Pd Ag2Se CdSe In2Se3 SnSe
SnSe2
-Sn 		Sb2Se3 Te +I Xe
Cs2Se BaSe * LuSe
Lu2Se3 		Hf TaSe2 WSe2
WSe3 		ReSe2 Os Ir PtSe2 Au HgSe Tl2Se PbSe Bi2Se3 Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg CnSe Nh Fl Mc Lv Ts Og
 
* LaSe
La2Se3 		CeSe
Ce2Se3 		PrSe
Pr2Se3 		NdSe
Nd2Se3 		Pm SmSe
Sm2Se3 		EuSe
Eu2Se3 		GdSe
Gd2Se3 		TbSe
Tb2Se3 		DySe
Dy2Se3 		HoSe
Ho2Se3 		ErSe
Er2Se3 		TmSe
Tm2Se3 		YbSe
Yb2Se3
** Ac ThSe2 Pa USe2 Np PuSe Am Cm Bk Cf Es Fm Md No
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H3BO3 He
Li2B4O7 Be B +(CO3)
+(C2O4) 		(NH4)3BO3
+NO3 		O +F Ne
Na2[B4O5(OH)4]·8H2O
NaBO2
NaBO3
Na3BO3
Na2B8O13 		Mg3(BO3)2 AlBO3 Si -PO4
+PO4 		+S
-SO4
+SO4 		+Cl Ar
K2B4O7•4H2O
KB5O8•4H2O 		Ca3(BO3)2 ScBO3 TiBO3 -VO4 Cr Mn3(BO3)2 Fe3(BO3)2
FeBO3
FeB(OH)4 		Co3(BO3)2 Ni3(BO3)2 Cu3(BO3)2 Znx(BO3)x GaBO3
-GaO4 		-GeO4 -AsO4 -SeO4
-SeO3
+Se 		+Br Kr
Rb3BO3
RbB11O16(OH)2
Rb[B5O6(OH)4]•2H2O 		Sr3(BO3)2 YBO3 ZrB2O5 Nb Mo Tc Ru Rh Pd Ag3BO3 Cd3(BO3)2 InBO3 Sn -SbBO4 -TeO4
-TeO3 		+I Xe
Cs3BO3
CsB5O8•4H2O 		BaB2O4 * Lu3B5O12 HfB2O5 Ta W Re Os Ir Pt Au Hg Tl3BO3 Pb3(BO3)2 BiBO3 Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* LaB3O6 CeB3O6 Pr4B10O21 NdBO3 Pm Sm Eu Gd Tb Dy4B6O15
Dy2B4O9 		Ho4B6O15
Ho2B4O9 		ErBO3 Tm3B5O12 Yb3B5O12
** Ac Th3(BO3)4 Pa U(BO3)2 Np Pu Am Cm Bk Cf[B6O8(OH)5] Es Fm Md No